在揮發(fā)性有機(jī)物（VOCs）排放控制領(lǐng)域，“沸石轉(zhuǎn)輪+蓄熱式熱氧化器（RTO）”組合工藝正成為石化、涂裝、印刷等行業(yè)的首選技術(shù)方案。該工藝通過(guò)吸附濃縮與高溫氧化的協(xié)同作用，實(shí)現(xiàn)廢氣中污染物的深度凈化，同時(shí)顯著降低能源消耗，推動(dòng)工業(yè)綠色轉(zhuǎn)型。

　　In the field of volatile organic compounds (VOCs) emission control, the combination process of "zeolite wheel+regenerative thermal oxidizer (RTO)" is becoming the preferred technical solution for industries such as petrochemicals, coatings, and printing. This process achieves deep purification of pollutants in exhaust gas through the synergistic effect of adsorption concentration and high-temperature oxidation, while significantly reducing energy consumption and promoting industrial green transformation.

　　工藝原理與技術(shù)特性

　　Process principles and technical characteristics

　　沸石轉(zhuǎn)輪作為前端處理單元，其核心是疏水性蜂窩狀沸石分子篩。當(dāng)含VOCs廢氣以低速通過(guò)轉(zhuǎn)輪吸附區(qū)時(shí)，沸石孔道內(nèi)的陽(yáng)離子交換位點(diǎn)通過(guò)物理吸附作用捕獲有機(jī)物分子，凈化氣排放濃度可降至50mg/m3以下。轉(zhuǎn)輪持續(xù)旋轉(zhuǎn)至脫附區(qū)，被180-220℃的熱風(fēng)解吸，濃縮比可達(dá)10-25倍。濃縮后的高濃度廢氣進(jìn)入RTO爐膛，在750-850℃條件下發(fā)生氧化反應(yīng)，生成CO?和H?O，熱回收效率超95%。

　　The zeolite wheel, as the front-end processing unit, has a hydrophobic honeycomb zeolite molecular sieve as its core. When VOCs containing exhaust gas passes through the rotary adsorption zone at low speed, the cation exchange sites in the zeolite pores capture organic molecules through physical adsorption, and the emission concentration of purified gas can be reduced to 50mg/m3 following. The wheel continues to rotate until it reaches the desorption zone, where it is desorbed by hot air at 180-220 ℃, with a concentration ratio of 10-25 times. The concentrated high concentration exhaust gas enters the RTO furnace and undergoes oxidation reaction at 750-850 ℃ to generate CO? And H? O, with a heat recovery efficiency of over 95%.

　　組合工藝的核心優(yōu)勢(shì)

　　The core advantages of combination technology

　　該工藝突破單一技術(shù)局限，形成“吸附-濃縮-氧化”的閉環(huán)系統(tǒng)。沸石轉(zhuǎn)輪解決RTO直接處理低濃度廢氣的能耗難題，RTO則消除沸石轉(zhuǎn)輪脫附氣二次污染風(fēng)險(xiǎn)。某汽車(chē)涂裝線應(yīng)用數(shù)據(jù)顯示，組合工藝使天然氣消耗量下降，VOCs排放濃度穩(wěn)定低于30mg/m3，遠(yuǎn)低于國(guó)家排放標(biāo)準(zhǔn)。在電子元件制造行業(yè)，該工藝成功處理含異丙醇、丙酮的復(fù)雜廢氣，非甲烷總烴去除率超99%。

　　This process breaks through the limitations of a single technology and forms a closed-loop system of "adsorption concentration oxidation". Zeolite wheel solves the energy consumption problem of direct treatment of low concentration exhaust gas by RTO, while RTO eliminates the risk of secondary pollution caused by desorption gas from zeolite wheel. The application data of a certain car painting line shows that the combination process reduces the consumption of natural gas and stabilizes the VOCs emission concentration below 30mg/m3 Far below the national emission standards. In the electronic component manufacturing industry, this process successfully treats complex exhaust gases containing isopropanol and acetone, with a non methane total hydrocarbon removal rate of over 99%.

　　節(jié)能降碳的經(jīng)濟(jì)價(jià)值

　　The economic value of energy conservation and carbon reduction

　　RTO配備的三床式蓄熱體采用陶瓷蜂窩材料，換熱面積達(dá)500m2/m3，熱回收率較傳統(tǒng)工藝提升。脫附熱風(fēng)利用RTO余熱加熱，減少額外能源輸入。某包裝印刷企業(yè)實(shí)踐表明，組合工藝較傳統(tǒng)催化燃燒技術(shù)年節(jié)約標(biāo)準(zhǔn)煤，減排二氧化碳當(dāng)量。對(duì)于間歇性排放工況，設(shè)備可接入智能控制系統(tǒng)，根據(jù)廢氣濃度自動(dòng)調(diào)節(jié)運(yùn)行參數(shù)，進(jìn)一步降低空載能耗。

　　The three bed thermal storage body equipped with RTO adopts ceramic honeycomb material, with a heat exchange area of 500m2/m3 The heat recovery rate is improved compared to traditional processes. Desorption hot air utilizes RTO waste heat for heating, reducing additional energy input. The practice of a packaging printing enterprise has shown that the combination process saves standard coal and reduces carbon dioxide equivalent emissions compared to traditional catalytic combustion technology. For intermittent emission conditions, the equipment can be connected to an intelligent control system to automatically adjust operating parameters based on exhaust gas concentration, further reducing no-load energy consumption.

　　安全性能與穩(wěn)定運(yùn)行

　　Safety performance and stable operation

　　針對(duì)沸石轉(zhuǎn)輪可能存在的脫附不完全風(fēng)險(xiǎn)，系統(tǒng)設(shè)置雙級(jí)冷凝裝置，將脫附氣溫度精準(zhǔn)控制在安全范圍內(nèi)。RTO配備泄爆片、阻火器等多重安全裝置，爐膛內(nèi)設(shè)置高溫限值連鎖保護(hù)。在化工園區(qū)應(yīng)用中，設(shè)備成功處理含氯苯、二甲苯的高危廢氣，未發(fā)生安全事故。對(duì)于含硅氧烷等易導(dǎo)致催化劑中毒的廢氣，轉(zhuǎn)輪吸附層可有效攔截，延長(zhǎng)RTO維護(hù)周期。

　　In response to the potential risk of incomplete desorption of zeolite rotors, the system is equipped with a two-stage condensing device to accurately control the desorption gas temperature within a safe range. RTO is equipped with multiple safety devices such as explosion-proof discs and flame arresters, and high-temperature limit interlock protection is installed in the furnace. In the application of chemical industrial parks, the equipment successfully processed high-risk waste gases containing chlorobenzene and xylene without any safety accidents. For exhaust gases containing siloxanes that are prone to catalyst poisoning, the rotary adsorption layer can effectively intercept and extend the maintenance cycle of RTO.

　　智能監(jiān)測(cè)與數(shù)字賦能

　　Intelligent monitoring and digital empowerment

　　設(shè)備搭載物聯(lián)網(wǎng)監(jiān)測(cè)平臺(tái)，實(shí)時(shí)采集溫度、壓力、濃度等30余項(xiàng)參數(shù)。通過(guò)邊緣計(jì)算模塊，系統(tǒng)可預(yù)測(cè)沸石吸附飽和度，提前規(guī)劃再生周期。在京津冀某工業(yè)區(qū)，監(jiān)管部門(mén)通過(guò)數(shù)字孿生平臺(tái)遠(yuǎn)程監(jiān)控12套組合裝置，實(shí)現(xiàn)排放數(shù)據(jù)分鐘級(jí)更新。

　　The device is equipped with an IoT monitoring platform, which collects more than 30 parameters such as temperature, pressure, and concentration in real time. Through the edge computing module, the system can predict the adsorption saturation of zeolite and plan the regeneration cycle in advance. In an industrial zone in the Beijing Tianjin Hebei region, regulatory authorities remotely monitor 12 sets of combined devices through a digital twin platform, achieving minute level updates of emission data.

　　隨著“雙碳”戰(zhàn)略推進(jìn)，該組合工藝正朝向更高效、更智能方向發(fā)展。新型鈦硅分子篩轉(zhuǎn)輪可實(shí)現(xiàn)脫附溫度降低，進(jìn)一步節(jié)能。RTO與熱泵技術(shù)耦合，可將余熱用于廠區(qū)供暖，系統(tǒng)綜合能效比提升。未來(lái)，數(shù)字孿生技術(shù)將構(gòu)建虛擬工藝模型，通過(guò)模擬不同工況優(yōu)化運(yùn)行參數(shù)，推動(dòng)工業(yè)廢氣治理向近零排放目標(biāo)邁進(jìn)。

　　With the advancement of the "dual carbon" strategy, this combination process is developing towards greater efficiency and intelligence. The new titanium silicate molecular sieve wheel can achieve a reduction in desorption temperature, further saving energy. The coupling of RTO and heat pump technology can use waste heat for heating in the factory area, improving the overall energy efficiency ratio of the system. In the future, digital twin technology will construct virtual process models, optimize operating parameters by simulating different working conditions, and promote industrial waste gas treatment towards the goal of near zero emissions.

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